Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex
نویسندگان
چکیده
Institut für Chemie, Technische Universitä Berlin, Germany. E-mail: matthias.driess@tu Department of Inorganic and Analytical Che and Economics, Szent Gellért tér 4, 1111 Bu † Electronic supplementary information ( and computational details, chara quantum-chemical calculation data as we ESI and crystallographic data in CIF 10.1039/c5sc02855h ‡ These authors contributed equally. Cite this: Chem. Sci., 2015, 6, 7143
منابع مشابه
Synthesis and characterization of an iron complex bearing a hemilabile NNN-pincer for catalytic hydrosilylation of organic carbonyl compounds.
A low-coordinate iron(ii) complex (CztBu(PztBu)2)Fe[N(SiMe3)2], 1 bearing an NNN-pincer ligand was prepared and fully characterized. Intramolecular C-H activation on the 5-position of a pyrazole at elevated temperatures was observed. Complex 1 was found to be an efficient and chemoselective pre-catalyst for the hydrosilylation of organo carbonyl substrates.
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